{"id":544596,"date":"2026-08-27T02:05:34","date_gmt":"2026-08-27T00:05:34","guid":{"rendered":"https:\/\/dev.phytocontrol.com\/uncategorized\/14-dmn-natural-presence-treatment-or-cross-contamination\/"},"modified":"2026-08-27T02:05:34","modified_gmt":"2026-08-27T00:05:34","slug":"14-dmn-natural-presence-treatment-or-cross-contamination","status":"publish","type":"post","link":"https:\/\/dev.phytocontrol.com\/en\/regulatory-watch\/14-dmn-natural-presence-treatment-or-cross-contamination\/","title":{"rendered":"1,4-DMN: natural presence, treatment or cross-contamination?"},"content":{"rendered":"\n<p class=\"wp-block-paragraph\"><\/p>\n\n<p class=\"wp-block-paragraph\">In a communication dated 13 July 2021, RELANA, a German organisation bringing together several laboratories, published a statement regarding 1,4-Dimethylnaphthalene (1,4-DMN) in potatoes and other plant products: <a href=\"https:\/\/www.relana-online.de\/wp-content\/uploads\/2021\/07\/relana-communication-note-21-03-about-14-DMN._210713.pdf\">Communication Note 21-03<\/a>.<\/p>\n\n<p class=\"wp-block-paragraph\">1,4-DMN is a sprout suppressant that has replaced Chlorpropham, banned in the EU since 8 January 2020. This synthetic molecule is naturally present in potatoes.<\/p>\n\n<p class=\"wp-block-paragraph\">According to this RELANA note, it belongs to the PAH chemical group, and its presence in the environment, and therefore in foodstuffs, could be caused by sources other than the use of a plant protection product. RELANA recommends that this information be taken into account when interpreting results in products other than conventionally grown potatoes.<\/p>\n\n<p class=\"wp-block-paragraph\">Regulation 396\/2005 currently sets an MRL of 15 mg\/kg for potatoes and 0.01 mg\/kg for other crops.<\/p>\n\n<p class=\"wp-block-paragraph\">According to the EFSA document \u201c<a href=\"https:\/\/efsa.onlinelibrary.wiley.com\/doi\/10.2903\/j.efsa.2014.3735\">Reasoned opinion on the setting of a new MRL for 1,4-dimethylnaphthalene in potatoes<\/a>\u201d, regarding other foodstuffs it states that:<\/p>\n\n<ul class=\"wp-block-list\">\n<li>The MRL of 0.01 mg\/kg does not cover the natural presence of 1,4-DMN.<\/li>\n\n\n\n<li>There is little information on the quantities naturally present in other plants; levels of up to 0.061 mg\/kg have been found in potatoes.<\/li>\n\n\n\n<li>Most natural background values in potatoes are below the LOQ, with a few positive values ranging between 0.015 and 0.061 mg\/kg.<\/li>\n\n\n\n<li>\u00a0<\/li>\n<\/ul>\n\n<p class=\"wp-block-paragraph\">The reliability of the data cannot be verified, as the growing conditions for the reported levels are not known. The number of data points is also not indicated in the EFSA opinion.<\/p>\n\n<p class=\"wp-block-paragraph\">In the EFSA document and in the thesis <a href=\"http:\/\/theses.gla.ac.uk\/319\/\">Oteef, Mohammed Dhafer Y. (2008) Analysis of the potato sprout inhibitor 1, 4-dimethylnapthalene: HPLC method development and applications. PhD thesis, University of Glasgow<\/a>, the natural 1,4-DMN content in potatoes is estimated at approximately 4 \u00b5g\/kg.<\/p>\n\n<p class=\"wp-block-paragraph\"><strong><u>Other potential source of 1,4-DMN<\/u><\/strong><\/p>\n\n<p class=\"wp-block-paragraph\">Petroleum oils that can be added to plant protection products as a co-formulant.<\/p>\n\n<p class=\"wp-block-paragraph\">A RELANA member laboratory detected 0.081 mg\/kg of 1,4-DMN in conventional parsley.<\/p>\n\n<p class=\"wp-block-paragraph\">After investigation, the identified source was the \u201c<em>solvent naphtha (petroleum), highly aromatic<\/em>\u201d present in the \u201c<em>Score<\/em>\u201d formulation based on difenoconazole.<\/p>\n\n<p class=\"wp-block-paragraph\">This interpretation is based on the presence of additional isomers of dimethylnaphthalene and monoethylnaphthalene that are characteristic of different petroleum fractions.<\/p>\n\n<p class=\"wp-block-paragraph\">Fertilisers may also contain petroleum oils.<\/p>\n\n<p class=\"wp-block-paragraph\"><strong><u>RELANA recommendations<\/u><\/strong><\/p>\n\n<p class=\"wp-block-paragraph\">For <strong><u>organic potatoes<\/u><\/strong>, RELANA recommends setting a threshold of <strong><u>0.05 mg\/kg<\/u><\/strong> for 1,4-DMN.<\/p>\n\n<p class=\"wp-block-paragraph\">For products other than potatoes, based on current knowledge, the presence of 1,4-DMN cannot be explained by natural occurrence. EFSA states that:<\/p>\n\n<p class=\"wp-block-paragraph\">\u201c<em>EFSA is therefore of the opinion that, for the rest of the plant commodities, a default value of 0.10 mg\/kg would be more appropriate to cover the possible natural background levels of 1,4-DMN in plants, although this proposal is not fully supported by a sufficient number of data. This default value of 0.1 mg\/kg was therefore used as input value for chronic consumer intake calculations.<\/em>\u201d<\/p>\n\n<p class=\"wp-block-paragraph\">Taking into account other possible sources of 1,4-DMN, RELANA proposes a tolerance of <strong><u>0.1 mg\/kg<\/u><\/strong> for products other than potatoes.<\/p>\n\n<p class=\"wp-block-paragraph\">This RELANA proposal is subject to approval and agreement by organic control bodies and the relevant competent authorities.<\/p>\n\n<p class=\"wp-block-paragraph\">Please note that your Phytocontrol laboratory is the only French laboratory offering 1,4-DMN analysis under COFRAC accreditation. You can consult our COFRAC technical appendix No. 1-1904, available in your customer area or on the COFRAC website.<\/p>\n\n<p class=\"wp-block-paragraph\">Need technical, regulatory or pricing information? Our customer service is available from 8am to 8pm, Monday to Friday, at <a href=\"tel:+33800900775\">+33 800 900 775<\/a> or <a href=\"mailto:service-clients@phytocontrol.com\">service-clients@phytocontrol.com<\/a><\/p>\n\n<p class=\"wp-block-paragraph\">And to keep up with all Phytocontrol news, join us on our <a href=\"https:\/\/www.linkedin.com\/company\/9369065\/\">LinkedIn<\/a> and <a href=\"https:\/\/www.facebook.com\/laboratoirePHYTOCONTROL\">Facebook<\/a> pages!<\/p>\n","protected":false},"excerpt":{"rendered":"<p>In a communication dated 13 July 2021, RELANA, a German organisation bringing together several laboratories,&hellip;<\/p>\n","protected":false},"author":8,"featured_media":13697,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"footnotes":""},"categories":[181],"tags":[],"class_list":["post-544596","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-regulatory-watch"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v28.4 (Yoast SEO v28.5) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>1,4-DMN: natural presence, treatment or cross-contamination? 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